I'm going to chime in but I'm not guaranteing I'm right...
But I was told (on here) that Mpix is WITHIN Miller's - like a small section of the same place.
I HAVE ordered the same pictures, from both places, and have not been able to see a difference personally. I know the back of the prints IS marked differently (Miller's adds copyright info and your studio name), and you can only get textures, etc at Millers, but overall Mpix can do about the same stuff (and less expensively). Millers does do free next day shipping (a feature that costs $10 from Mpix).
Personally, I use both. Just depends on what I want and the quantity of stuff I'm ordering.
I have discovered, though, that I REALLY like the ordering system in Millers better than Mpix, by about 10X - it's just easier!
Canon 5D, 400D as back up. 580 EX II, 24-70 f2.8L, 70-200 f2.8L IS USM, 50mm f1.8, 80-200 f3.5 Canon ALL the way!!
